No, that is not an option. The presence status for the platform are what they are and there is no way to override how they work. While there are ideas to be able to make custom presence in the ideas lab On Queue as far as I'm aware this will always be the mechanism that makes an agent able to receive ACD calls and digital interactions.
I'm assuming in your prior platform, "Available" was the presence that allowed users to take ACD routed calls? In my opinion it's just going to be a training requirement that they learn that on-queue is the equivalent to Available in the prior system.
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Steve Alix
EDCi
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